Extraction-spectrophotometric determination of palladium(II) with di-2-pyridyl ketone benzoylhydrazone.

Extraction - Spectrophotometric Determination of Palladium with Tetrabutyl Ammonium Iodide

A sensitive and selective extraction - spectrophotometric method for the determination of trace amounts of palladium is reported. The method is based on quantitative extraction of brownish tetrabutylammoium tetraiodopalladium (II) ion pair into a small valume of chloroform at pH 1.3-12.0, followed by spectrophotometric measurements. The Beer's law is obeyed over the range 0.02-1.09 <em...

Selective extraction spectrophotometric determination

Di-2-pyridyl ketone 2-furoylhydrazone as a reagent for the fluorimetric determination of low concentrations of gallium and its application to biological samples.

Di-2-pyridyl ketone 2-furoylhydrazone (DPFH) has been examined as a sensitive spectrofluorimetric reagent for the determination of gallium. 4 rapid procedure for the fluorimetric determination of th i s ion at the 2-800 ng ml-1 level at pH 3.S4.1 (Aex 395 nm, he, 473 nm) has been established. The detection limit is 2 ng ml-1 and the relative standard deviation is 2.4% (40 p.p.b. of gallium). In...

Solvent Extraction and Spectrophotometric Determination of Magnesium by Paratoly l-2-Thenohydroxamic Acid and Quinalizarin

Magnesium is extracted with a chloroform solution of N-p-tolyl-2- thenohydroxamic acid (PTTHA) from aqueous solution of pH 9.5 .Mg-PTTHA complex is colourless and the colour is developed by adding quinalizarin into the extract. lmax and e of the complex are 590nm and 2.8´103 Lmol -1cm-1respectively.Most common  ions do not interfere in the determination of magnesi...

Extraction and Spectrophotometric Determination of Copper (Ii) with 1-(2-Metoxiphenylamin)-3-Metoksipropanthiol-2

The alloys of copper find extensive use in automobile radiators, heat exchangers, home heating systems and panels for absorbing solar energy. Copper (II) is a biologically active metal; its compounds affect the vital activity of plant and animal organisms. Copper is one of essential elements required for normal human metabolism [1]. Copper (II) is known to play a significant role in biological ...